Answer:
Option C
Explanation:
The thermal decomposition of given compounds is shown below
(NH4)2Cr2O7 $ \underrightarrow{\triangle}$ N2 + 4H2O + Cr2O3
NH4NO2 $\underrightarrow{\triangle}$ N2 + 2H2O
(NH4)2SO4 $\underrightarrow{\triangle}$ 2NH3 + H2SO4
Ba(N3)2 $\rightarrow$ Ba + 2N2
Thus, only (NH4)2SO4 does not gives N2 on heating (It gives NH3). While the rest of the given compounds gives N2 on their thermal decomposition.